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Pure Appl. Chem., Vol. 68, No. 7, pp. 1491-1494, 1996

MACROMOLECULAR DIVISION

COMMISSION ON POLYMER CHARACTERIZATION AND PROPERTIES

Working Party on Modeling of Polymerization Kinetics and Processes

 

Critically-Evaluated Propagation Rate Coefficients in Free Radical Polymerizations - I. Styrene and methyl methacrylate

(Technical Report)

R.G. Gilbert

Synopsis: Critically evaluated rate coefficients and confidence limits, with derived Arrhenius parameters and confidence ellipses, are reported for the propagation rate coefficients of styrene and methyl methacrylate at low conversion in bulk. Data were obtained by pulsed-laser polymerization in several laboratories, and obey the consistency criteria established for this technique. These results provide useful ''benchmarks'' for measurements of propagation rate coefficients by other workers and other techniques.

[full text - pdf 266 kB]

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