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Pure Appl. Chem. Vol. 73, No. 3, pp. 491-495 (2001)

Pure and Applied Chemistry

Vol. 73, Issue 3

New polymeric photosensitizers*

Maria Nowakowska**, Mariusz Kepczynski, and Krzysztof Szczubialka

Faculty of Chemistry, Jagiellonian University, 30-060 Kraków, Ingardena 3, Poland

Abstract: Novel polymeric photosensitizers for singlet oxygen production in water are described. The polymers contain rose bengal (4,5,6,7-tetrachloro-2',4',5',7'­tetraiodo-fluorescein) chromophores covalently attached to the polymer chain. The quantum yields of singlet oxygen formation and photooxidation of phenol in water have been determined. The methods of separation of photosensitizer from the reactants after completion of reaction have been established.

*Lecture presented at the XVIIIth IUPAC Symposium on Photochemistry, Dresden, German , 22-27 July 2000.Other presentations are published in this issue, pp.395-548.
**Corresponding author

 


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