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Pure Appl. Chem. 75(2-3), 235-249, 2003

Pure and Applied Chemistry

Vol. 75, Issue 2-3

Progress in fumagillin synthesis

W. Picoul, O. Bedel, A. Haudrechy, and Y. Langlois

Laboratoire de Synthèse des Substances Naturelles,Associé au CNRS, Université de Paris-Sud, F-91405 Orsay, France

Abstract: After a brief account of the syntheses previously described in literature, several approaches of the antiangiogenic sesquiterpene fumagillin are described. Particularly, a Claisen–Ireland ring-closing metathesis strategy allowed the stereoselective preparation of several advanced intermediates in the fumagillin synthesis.

*Pure Appl.Chem. 75, 141�419 (2003). An issue of reviews and research papers based on lectures presented at the 23rd IUPAC International Symposium on the Chemistry of Natural Products, Florence, Italy, 28 July � 2 August 2002.


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