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Pure Appl. Chem. Vol. 74, No. 1, pp. 151-157 (2002)

Pure and Applied Chemistry

Vol. 74, Issue 1

Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon­carbon bond formation*

Ei-ichi Negishi and Shouquan Huo

Herbert C. Brown Laboratories of Chemistry, Purdue University, West Lafayette, IN 47907-1393, USA

Abstract: The discovery, methodological developments, including those for separation­purification of chiral flexible primary alcohols, and their applications to the syntheses of some natural products of the titled reaction are discussed.

*Lecture presented at the 11th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-11), Taipei, Taiwan, 22-26 July 2001. Other presentations are presented in this issue, pp.1-186.
**Corresponding author.


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