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Pure Appl. Chem. Vol. 73, No. 3, pp. 469-474 (2001)

Pure and Applied Chemistry

Vol. 73, Issue 3

Electron-transfer dyads suitable for novel self-assembled light-harvesting antenna/electron-transfer devices*

Alfred R. Holzwarth**, Martin Katterle, Marc G. Müller, Ying-Zong Ma, and Valentin Prokhorenko

Max-Planck-Institut für Strahlenchemie, Stiftstraße 34-36, 45470 Mülheim/Ruhr, Germany

Abstract: The synthesis and photophysical and photochemical characterization of four novel bacterio-chlorin-fullerene dyads with fullerene C60 coupled at various positions and by various bridges to the chlorin ring are described. All dyads undergo rapid charge separation in the sub-picosecond to picosecond time range as characterized by time-resolved fluorescence and transient absorption spectroscopy.

*Lecture presented at the XVIIIth IUPAC Symposium on Photochemistry, Dresden, German , 22-27 July 2000.Other presentations are published in this issue, pp.395-548.
**Corresponding author


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