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Pure Appl. Chem. Vol. 73, No. 3, pp. 443-447 (2001)

Pure and Applied Chemistry

Vol. 73, Issue 3

Organometallic alkane and noble-gas complexes in conventional and supercritical fluids*

Gavin I. Childs, David C. Grills, Xue Z. Sun, and Michael W. George**

School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK

Abstract: Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.

*Lecture presented at the XVIIIth IUPAC Symposium on Photochemistry, Dresden, German , 22-27 July 2000.Other presentations are published in this issue, pp.395-548.
** Corresponding author


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