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Pure Appl. Chem. Vol.
73, No. 2, pp. 305-309 (2001)
Pure and Applied
Vol. 73, Issue
Isolobal displacement methodology for the synthesis of transition-metal
cluster complexes containing various biscyclopentadienyl ligands*
Li-Cheng Song** and Dian-Shun Guo
Department of Chemistry, State Key Laboratory of Elemento-Organic
Chemistry, Nankai University, Tianjin 300071, China
Abstract: The isolobal displacement methodology for the synthesis
of biscyclopentadienyl-bridged transition-metal cluster complexes has
been developed. This methodology involves various isolobal displacement
reactions between tetrahedral cluster substrates and Mo/W-containing
isolobal reagents, leading to a series of linear biscyclopentadienyl-bridged
cluster complexes and cyclic biscyclopentadienyl-bridged cluster crown
* Lecture presented at the XIXth International Conference
on Organometallic Chemistry (XIX ICOMC) , Shanghai, China, 23-28 July
2000. Other presentations are published in this issue, pp. 205-376.
** Corresponding author
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