Number: 2003-018-1-500
Title: Mutual solubility of hydrocarbons and water
(update of SDS Vol 37 & 38)
Series: Solubility Data Series; editor-in-chief: Mark
Salomon
Task Group
Chairman: Andrzej
Maczynski
Members: Marian Goral,
Barbara Wisniewska-Goclowska,
David Shaw, and Mark
Salomon
Completion Date: 2006 - project completed
Objective:
This project will update and re-evaluate solubility data for all
C-5 and higher hydrocarbons with water. These systems were previously
treated in Volumes 37 and 38 of the Solubility Data Series, which were
published in 1988 and quickly went out of print. The results of this
work will be prepared in the standard format of the IUPAC-NIST Solubility
Data Series for publication in the Journal of Physical and Chemical
Reference Data and for inclusion in a web-accessible database being
prepared by the US National Institute of Standards and Technology (NIST).
Description:
Under the direction of the Subcommittee on Solubility and Equilibrium
Data (SSED) of the Analytical Chemistry Division, the IUPAC Solubility
Data Project (SDP) compiles and critically evaluates data on chemical
solubility and disseminates the resulting information to the widest
possible range of users by traditional (printed on paper) and electronic
(web-accessible database) means.
The systems to be covered by this project do not fit within the priority
focus areas identified in the phantom proposal. However, they are of
great interest both to environmental scientists concerned with the fate
and effects of petroleum pollution and to industrial chemists dealing
with petroleum and petrochemicals. Because of the importance of these
systems they were treated early in the SDP. The resulting volumes (SDS
37 and 38) were published 15 years ago and are now both out of date
and out of print.
This project will update the previous volumes by compiling new data
from approximately 50 published sources and reevaluate all systems where
this is appropriate.
Progress:
In addition to the standard evaluation criteria used throughout the
Solubility Data Series, a new method based on the evaluation of all
experimental data for a given series of hydrocarbons and new models
for Equation of State were used.
The work has been divided into 12 parts, all of which are in the hands
of the Editor-in-Chief of the Solubility Data Project or have been submitted
for publication in the Journal of Physical and Chemical Reference
Data (JPCRD). Parts 1-5 correspond to systems from volume 37, parts
6-11 to systems from volume 38 and part 12 to systems of hydrocarbons
in seawater.
> Nov 2004 report update (pdf
file - 11KB)
Parts 1 to 4 are published in J. Phys. Chem. Ref. Data 2005,
34, No. 2 > references
Parts 5 and 6 are published in J. Phys. Chem. Ref. Data 2005,
34, No. 3 > references
Parts 7 and 8 are published in J. Phys. Chem. Ref. Data 2005,
34, No. 4 > references
Parts 9 and 10 are published in J. Phys. Chem. Ref. Data 2006,
35, No. 1> references
Parts 11 and 12 are published in J. Phys. Chem. Ref. Data 2006,
35, No. 2> references
Project completed.
Last Update: 29 May 2006